If the newbro does want to join Villore accords make sure you know a little about PVP first. The alliance doesn't treat very new people well, was my first alliance/corp when I first joined the game. Not good meaning they did a piss poor job teaching you how to play other than yelling at you for your win/loss ratio.
The other options will become very apparent with using the channel OOC within eve to meet and talk to people about what you want to do and who to do it with.
Just want to chime in real quick. 5+ year GMVA vet and director here.
First, I'm sorry Liuni had a bad experience starting out the game in one of our corps. I'm glad you stuck with EVE and are still around.
Second, I'd like to respectfully point out that the experience Liuni had in one GMVA corp for 3 months back in 2012/2013 might not be representative of GMVA today. We have six member corps, all with different player cultures, different leadership personalities, and different levels of development. We have loads of new players joining all the time, we value their contributions, and we want them to grow up strong to kill lots of squids.
I'm pretty distressed to hear about anyone in our alliance "yelling about win/loss ratios" at a new player, even if it was four years ago. That's absolutely not the culture I'm used to in Moira, where I was and still am prone to plenty of derp losses. I also know [EL-G] also has some really nice RP people these days, like Aedre and Tarek.
Anyway, that said the advice to be prepared for pvp if you want to join us is well given. Gallente Militia in general tends to be a place where free atrons rain from the heavens upon new players with the expectation that they blow up often.